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群馬大学（Gunma University） >
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0003 群馬大学教育学部紀要 自然科学編 >
第51巻 (2003) >
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http://hdl.handle.net/10087/843
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| Title: | X-ray photoemission band spectra of CrCl3 and CrBr3 |
| Authors: | Okusawa, Makoto |
| Issue Date: | 2003 |
| Publisher: | 群馬大学教育学部 |
| Citation: | 群馬大学教育学部紀要 自然科学編. 51, 71-78 (2003) |
| Abstract: | The valence-band spectra of CrCl3 and CrBr3 have been measured by x-ray photoemission spectroscopy. Neither the appearance of a satellite nor the extreme narrowing of a main line are found in contrast to the case of Ni-compounds. With regard to the appearance of the satellite these halides contrast with Cr2O3 where the satellite accompanies the main line, though both of them belong to the trivalent Cr-compound. Ligand-field theory without taking account of charge transfer is applicable to describe the observed spectra, and an existing energy-band calculation does not appear to explain the results obtained here. |
| URI: | http://hdl.handle.net/10087/843 |
| Appears in Collections: | 第51巻 (2003)
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