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Please use this identifier to cite or link to this item: http://hdl.handle.net/10087/843

Title: X-ray photoemission band spectra of CrCl3 and CrBr3
Authors: Okusawa, Makoto
Issue Date: 2003
Publisher: 群馬大学教育学部
Citation: 群馬大学教育学部紀要 自然科学編. 51, 71-78 (2003)
Abstract: The valence-band spectra of CrCl3 and CrBr3 have been measured by x-ray photoemission spectroscopy. Neither the appearance of a satellite nor the extreme narrowing of a main line are found in contrast to the case of Ni-compounds. With regard to the appearance of the satellite these halides contrast with Cr2O3 where the satellite accompanies the main line, though both of them belong to the trivalent Cr-compound. Ligand-field theory without taking account of charge transfer is applicable to describe the observed spectra, and an existing energy-band calculation does not appear to explain the results obtained here.
URI: http://hdl.handle.net/10087/843
Appears in Collections:第51巻 (2003)

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