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Please use this identifier to cite or link to this item: http://hdl.handle.net/10087/930

Title: Derivative Process of Inversion of Kirkwood-Buff Theory in Binary Liquid Mixtures
Authors: Nakagawa, Tetsuo
Umemura, Myco
Issue Date: 2004
Publisher: 群馬大学教育学部
Citation: 群馬大学教育学部紀要 自然科学編. 52, 123-135 (2004)
Abstract: The Kirkwood-Buff (KB) integrals are calculated using thermodynamic properties such as isothermal compressibilities, partial molar volumes (or excess molar volumes), and partial vapor pressures (or activity coefficients, or excess molar Gibbs energies) with the help of the inversion of the KB theory about liquid mixtures. Matteoli and Lepoli have already proposed the useful formulae with which the KB integrals are easily estimated in binary liquid mixtures. However, the derivative process of these formulae is still obscure. In this paper, the Matteoli-Lepoli formulae are obtained from the modified KB equations by Ben-Nairn via Donkersloot equations, and consequently the detailed derivative process is clarified.
URI: http://hdl.handle.net/10087/930
Appears in Collections:第52巻 (2004)

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